Counterbalancing Central vs. Peripheral Face Presentation in PsychoPy (EEG Experiment)

Counterbalancing trial types is normally done by creating a spreadsheet with all possible combinations of the key variables.

Emotional face centre (25% with scrambled left, 25% with scrambled right), left (25%), right (25%)

That seems to be just four trial types. Is the issue that you would like the actual faces used to be randomised independently? If so, have a look at my independent randomisation demo.